Thermodynamic modeling of the V–Si system supported by key experiments

Chao Zhang, Yong Du, Wei Xiong, Honghui Xu, Philip Nash, Yifang Ouyang, Rongxiang Hu

Calphad 32 (2) 320-325 (2008) · Elsevier BV

DOI: 10.1016/j.calphad.2007.12.005

Data: JSON record · id doi:10.1016/j.calphad.2007.12.005 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 47 released values
• cited as the original source of values
• assessment behind a TDB file: SiV-08Zha.tdb (Si–V)

Systems

V, Si–V, Si–Ta–V

Evidence in ORCHID

47 values read from this paper (43 accepted), from 3 tables and 4 text passages.

24 values in 2 other papers cite this work as their source.

ESPEI datasets derived: 33 (derived/invariant-brackets/SI-V/SiV-08Zha.zpf-00.json …).

Phase-registry phases citing it: phase:si-v:a4-diamond, phase:si-v:bcc-a2, phase:si-v:fcc-a1, phase:si-v:hcp-a3, phase:si-v:liquid, phase:si-v:si2v-c40, phase:si-v:si3v5-d8m, phase:si-v:si5v6, phase:si-v:siv3-a15

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 46 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (20)

• Solid-State Phase Equilibria of the V-Si-Gd System at 973 K (700 °C) (2014) [crossref_reference_list]
• Thermodynamic Assessment of the Si-Ta and Si-W Systems (2009) [crossref_reference_list]
• Si-V (Silicon-Vanadium) (2010) [crossref_reference_list]
• Phase Equilibria of the Er-Si-V Ternary System at 1173 K (2012) [crossref_reference_list]
• Experimental Investigation and Thermodynamic Extrapolation of the Si-V-Zn System (2015) [crossref_reference_list]
• Phase Equilibria in the V-Rich Region of the V-Si-B System at 1400 °C (2025) [crossref_reference_list]
• Thermodynamic modeling of the V–Cr–Si system (2015) [crossref_reference_list]
• The reassessment of the Al-V system and new assessment of the Al-Si-V system (2017) [crossref_reference_list]
• Thermodynamic modeling of the V-Si-B system (2017) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Phase equilibria in the Al–Si–V system (2010) [crossref_reference_list]
• Phase equilibria in the Al–Si–V system: The vanadium rich part (2011) [crossref_reference_list]
• The phase equilibria of the Ti–V–M (M = Si, Nb, Ta) ternary systems (2020) [crossref_reference_list]
• Experimental study of the liquidus surface in the V-rich portion of the V-Si-B system (2020) [crossref_reference_list]
• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) [crossref_reference_list]
• The system Ta–V–Si: Crystal structure and phase equilibria (2012) [crossref_reference_list]
• The system Ta–V–Si: Thermodynamic modeling (2013) [crossref_reference_list]
• Solidification processes of as-cast alloys and phase equilibria at 1 300 °C of the Nb–Si–V ternary system (2020) [crossref_reference_list]
• Mo-Si-V Ternary Phase Diagram Evaluation (2013) [crossref_reference_list]
• B-Si-V Ternary Phase Diagram Evaluation (2024) [crossref_reference_list]

References (Crossref, publisher-deposited) (13)

• Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K (1999) [crossref_reference_list]
• Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si) (2000) [crossref_reference_list]
• The Si−V (Silicon-Vanadium) system (1981) [crossref_reference_list]
• The Si−V (Silicon-Vanadium) system: Addendum (1985) [crossref_reference_list]
• An investigation on the thermodynamic stability of V6Si5 (2007) [crossref_reference_list]
• The V3Si phase: Type of formation and homogeneity range (1982) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Assessment of the CrSi System (1994) [crossref_reference_list]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) [crossref_reference_list]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• A thermodynamic description of the B–Co system: modeling and experiment (2002) [crossref_reference_list]

Cited for values by (2)

• The system Ta–V–Si: Thermodynamic modeling (2013) — 18 values [orchid_extraction]
• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) — 6 values [orchid_extraction]

Cites (values carry this citation) (8)

• An investigation on the thermodynamic stability of V6Si5 (2007) — 6 values [orchid_extraction]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) — 4 values [orchid_extraction]
• The V3Si phase: Type of formation and homogeneity range (1982) — 3 values [orchid_extraction]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 2 values [orchid_extraction]
• Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K (1999) — 1 values [orchid_extraction]
• Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si) (2000) — 1 values [orchid_extraction]
• The Si−V (Silicon-Vanadium) system (1981) — 1 values [orchid_extraction]
• The Si−V (Silicon-Vanadium) system: Addendum (1985) — 1 values [orchid_extraction]

TDB files modelling its system (1)

• tdb:SiV-08Zha.tdb [sgte_tdb_header]

Reassessed by (2)

• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) [citation+same-system]
• The system Ta–V–Si: Thermodynamic modeling (2013) [citation+same-system]

Data papers used (8)

• An investigation on the thermodynamic stability of V6Si5 (2007) — 6 values [orchid_extraction]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) — 4 values [orchid_extraction]
• The V3Si phase: Type of formation and homogeneity range (1982) — 3 values [orchid_extraction]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 2 values [orchid_extraction]
• Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K (1999) — 1 values [orchid_extraction]
• Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si) (2000) — 1 values [orchid_extraction]
• The Si−V (Silicon-Vanadium) system (1981) — 1 values [orchid_extraction]
• The Si−V (Silicon-Vanadium) system: Addendum (1985) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (2)

• The system Ta–V–Si: Thermodynamic modeling (2013) — 18 values [orchid_extraction]
• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) — 6 values [orchid_extraction]