The system Ta–V–Si: Thermodynamic modeling

P. Broz, A.U. Khan, H. Niu, X.-Q. Chen, D. Li, J. Vrestal, J. Bursik, P. Rogl

Journal of Solid State Chemistry 199 171-180 (2013) · Elsevier BV

DOI: 10.1016/j.jssc.2012.12.003

Data: JSON record · id doi:10.1016/j.jssc.2012.12.003 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 157 released values
• cited as the original source of values
• assessment behind a TDB file: SiV-13Bro.tdb (Si–V), TaV-13Bro.tdb (Ta–V)
• discovery lead (found by Crossref assessment discovery, not read): rank 514, score 109; systems named in title: Si–Ta–V

Systems

Ta, V, Si–Ta, Si–V, Ta–V, Si–Ta–V

Evidence in ORCHID

157 values read from this paper (156 accepted), from 2 tables and 1 text passages.

6 values in 1 other papers cite this work as their source.

Phase-registry phases citing it: phase:si-v:a4-diamond, phase:si-v:bcc-a2, phase:si-v:fcc-a1, phase:si-v:hcp-a3, phase:si-v:liquid, phase:si-v:si2v-c40, phase:si-v:si3v5-d8m, phase:si-v:si5v6, phase:si-v:siv3-a15, phase:ta-v:bcc-a2, phase:ta-v:c14-laves, phase:ta-v:c15-laves, phase:ta-v:fcc-a1, phase:ta-v:hcp-a3, phase:ta-v:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 7 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (4)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Physical properties of TiMn2 and interaction with refractory TiN (system Ti-Mn-N) (2018) [crossref_reference_list]
• Experimental investigation and thermodynamic assessment of phase equilibria in the ternary Zr–Ta–Si system (2026) [crossref_reference_list]
• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) [crossref_reference_list]

References (Crossref, publisher-deposited) (29)

• Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K (1999) [crossref_reference_list]
• Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si) (2000) [crossref_reference_list]
• Low temperature specific heat of VSi2, NbSi2, and TaSi2 (1993) [crossref_reference_list]
• Untersuchungen in den Dreistoffsystemen: Molybdän-Silizium-Bor, Wolfram-Silizium-Bor und in dem System: VSi2−TaSi2 (1957) [crossref_reference_list]
• Tern�re Phasen mit MgZn2?Ty (1965) [crossref_reference_list]
• Das Verhalten metallreicher, hochschmelzender Silizide gegen�ber Bor, Kohlenstoff, Stickstoff und Sauerstoff (1956) [crossref_reference_list]
• The Ta-V (Tantalum-Vanadium) system (1983) [crossref_reference_list]
• An investigation on the thermodynamic stability of V6Si5 (2007) [crossref_reference_list]
• Thermodynamic Assessment of the Si-Ta and Si-W Systems (2009) [crossref_reference_list]
• Si-V (Silicon-Vanadium) (2010) [crossref_reference_list]
• The heats of formation of some transition metal silicides (1955) [crossref_reference_list]
• Une famille de siliciures ternaires isotypes de V6Si5: (T, T′)6Si5 OÙ T = V, Cr, Mn ET T′ = Ti, Nb, Ta (1977) [crossref_reference_list]
• Si-Stabilised C14 laves phases in the transition metal systems (1978) [crossref_reference_list]
• Investigation of the ternary systems Nb-V-H and Ta-V-H (1986) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• SGTE data for pure elements (1991) [crossref_reference_list]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) [crossref_reference_list]
• Thermodynamic modeling of the V–Si system supported by key experiments (2008) [crossref_reference_list]
• Thermodynamic modeling of Laves phases in the Ta–V system: Reassessment using first-principles results (2011) [crossref_reference_list]
• The system Ta–V–Si: Crystal structure and phase equilibria (2012) [crossref_reference_list]
• A thermodynamic evaluation of the Ta–V system (2004) [crossref_reference_list]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• From ultrasoft pseudopotentials to the projector augmented-wave method (1999) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes (1969) [crossref_reference_list]
• Stability of Crystal Structure of (Fe, V)<SUB>3</SUB>M and (Fe, Ni)<SUB>3</SUB>M (M=Si, Ge, Sn) and Its Analysis Based on Rigid Band Model (1986) [crossref_reference_list]
• Structure des phases binaires V6Si5 et Ti6Ge5 (1970) [crossref_reference_list]

Cited for values by (1)

• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) — 6 values [orchid_extraction]

Cites (values carry this citation) (18)

• The system Ta–V–Si: Crystal structure and phase equilibria (2012) — 21 values [orchid_extraction]
• Thermodynamic modeling of the V–Si system supported by key experiments (2008) — 18 values [orchid_extraction]
• Thermodynamic Assessment of the Si-Ta and Si-W Systems (2009) — 15 values [orchid_extraction]
• The Ta-V (Tantalum-Vanadium) system (1983) — 5 values [orchid_extraction]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) — 5 values [orchid_extraction]
• Low temperature specific heat of VSi2, NbSi2, and TaSi2 (1993) — 4 values [orchid_extraction]
• Si-Stabilised C14 laves phases in the transition metal systems (1978) — 4 values [orchid_extraction]
• Thermodynamic modeling of Laves phases in the Ta–V system: Reassessment using first-principles results (2011) — 4 values [orchid_extraction]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 4 values [orchid_extraction]
• An investigation on the thermodynamic stability of V6Si5 (2007) — 3 values [orchid_extraction]
• The heats of formation of some transition metal silicides (1955) — 3 values [orchid_extraction]
• Une famille de siliciures ternaires isotypes de V6Si5: (T, T′)6Si5 OÙ T = V, Cr, Mn ET T′ = Ti, Nb, Ta (1977) — 3 values [orchid_extraction]
• Structure des phases binaires V6Si5 et Ti6Ge5 (1970) — 3 values [orchid_extraction]
• Untersuchungen in den Dreistoffsystemen: Molybdän-Silizium-Bor, Wolfram-Silizium-Bor und in dem System: VSi2−TaSi2 (1957) — 2 values [orchid_extraction]
• Tern�re Phasen mit MgZn2?Ty (1965) — 2 values [orchid_extraction]
• The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes (1969) — 2 values [orchid_extraction]
• Investigation of the ternary systems Nb-V-H and Ta-V-H (1986) — 1 values [orchid_extraction]
• Stability of Crystal Structure of (Fe, V)<SUB>3</SUB>M and (Fe, Ni)<SUB>3</SUB>M (M=Si, Ge, Sn) and Its Analysis Based on Rigid Band Model (1986) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:SiV-13Bro.tdb [sgte_tdb_header]
• tdb:TaV-13Bro.tdb [sgte_tdb_header]

Reassessed by (1)

• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (3)

• Thermodynamic modeling of the V–Si system supported by key experiments (2008) [citation+same-system]
• Thermodynamic modeling of Laves phases in the Ta–V system: Reassessment using first-principles results (2011) [citation+same-system]
• A thermodynamic evaluation of the Ta–V system (2004) [citation+same-system]

Data papers used (18)

• The system Ta–V–Si: Crystal structure and phase equilibria (2012) — 21 values [orchid_extraction]
• Thermodynamic modeling of the V–Si system supported by key experiments (2008) — 18 values [orchid_extraction]
• Thermodynamic Assessment of the Si-Ta and Si-W Systems (2009) — 15 values [orchid_extraction]
• The Ta-V (Tantalum-Vanadium) system (1983) — 5 values [orchid_extraction]
• Miedema’s model revisited: The parameter for Ti, Zr, and Hf (2006) — 5 values [orchid_extraction]
• Low temperature specific heat of VSi2, NbSi2, and TaSi2 (1993) — 4 values [orchid_extraction]
• Si-Stabilised C14 laves phases in the transition metal systems (1978) — 4 values [orchid_extraction]
• Thermodynamic modeling of Laves phases in the Ta–V system: Reassessment using first-principles results (2011) — 4 values [orchid_extraction]
• Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry (1998) — 4 values [orchid_extraction]
• An investigation on the thermodynamic stability of V6Si5 (2007) — 3 values [orchid_extraction]
• The heats of formation of some transition metal silicides (1955) — 3 values [orchid_extraction]
• Une famille de siliciures ternaires isotypes de V6Si5: (T, T′)6Si5 OÙ T = V, Cr, Mn ET T′ = Ti, Nb, Ta (1977) — 3 values [orchid_extraction]
• Structure des phases binaires V6Si5 et Ti6Ge5 (1970) — 3 values [orchid_extraction]
• Untersuchungen in den Dreistoffsystemen: Molybdän-Silizium-Bor, Wolfram-Silizium-Bor und in dem System: VSi2−TaSi2 (1957) — 2 values [orchid_extraction]
• Tern�re Phasen mit MgZn2?Ty (1965) — 2 values [orchid_extraction]
• The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes (1969) — 2 values [orchid_extraction]
• Investigation of the ternary systems Nb-V-H and Ta-V-H (1986) — 1 values [orchid_extraction]
• Stability of Crystal Structure of (Fe, V)<SUB>3</SUB>M and (Fe, Ni)<SUB>3</SUB>M (M=Si, Ge, Sn) and Its Analysis Based on Rigid Band Model (1986) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamic investigation of phase equilibria in Al–Si–V system (2018) — 6 values [orchid_extraction]