Thermodynamic Reassessment of the Binary Cu-Sn, Cu-P, and Sn-P and Ternary Cu-Sn-P Systems

Katsunari Oikawa, Nobufumi Ueshima

Journal of Phase Equilibria and Diffusion 45 (3) 547-566 (2024) · Springer Science and Business Media LLC

DOI: 10.1007/s11669-024-01112-z

Data: JSON record · id doi:10.1007/s11669-024-01112-z · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 48 released values
• assessment behind a TDB file: CuP-24Oik.tdb (Cu–P), CuSn-24Oik.tdb (Cu–Sn), SnP-24Oik.tdb (P–Sn)
• discovery lead (found by Crossref assessment discovery, not read): rank 132, score 119; systems named in title: Cu–P–Sn

Systems

Cu–P, Cu–Sn, P–Sn, Cu–P–Sn

Evidence in ORCHID

48 values read from this paper (47 accepted), from 3 tables and 0 text passages.

ESPEI datasets derived: 1 (experimental/CU-P/CuP-24Oik.zpf-00.json).

Phase-registry phases citing it: phase:cu-p:bcc-a2, phase:cu-p:cu2p7, phase:cu-p:cu3p-d021, phase:cu-p:cup2, phase:cu-p:fcc-a1, phase:cu-p:gas, phase:cu-p:hcp-a3, phase:cu-p:liquid, phase:cu-p:p-red, phase:cu-p:p-white, phase:cu-sn:a4-diamond, phase:cu-sn:a5-bct, phase:cu-sn:bcc-4sl, phase:cu-sn:bcc-a2, phase:cu-sn:cu10sn3, phase:cu-sn:cu3sn-l, phase:cu-sn:cu41sn11, phase:cu-sn:cu6sn5-b81, phase:cu-sn:cu6sn5-l, phase:cu-sn:fcc-a1 …

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 8 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (3)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• The experimental phase equilibria studies of the Cu-Sn-S system (2026) [crossref_reference_list]
• Thermodynamic Reassessment and Phase Diagram Calculations of the Fe–P and Fe–C–P Systems (2026) [crossref_reference_list]

References (Crossref, publisher-deposited) (25)

• Beiträge zur systematischen Verwandtschaftslehre XXVIII. Über die Bildungswärmen intermetallischer verbindungen V. Kobalt‐ Aluminiumlegierunge n; Kupferlegierungen (1924) [crossref_reference_list]
• Über das Zustandsschaubild der CuSnP‐Legierungen (1933) [crossref_reference_list]
• P-Sn (phosphorus-tin) (1993) [crossref_reference_list]
• Phase diagram of the Sn–P system (2018) [crossref_reference_list]
• On differential thermal analyzer curves for the melting and freezing of alloys (2002) [crossref_reference_list]
• Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems (2004) [crossref_reference_list]
• Experimental and thermodynamic assessment of Sn-Ag-Cu solder alloys (2000) [crossref_reference_list]
• Experimental Investigation and Thermodynamic Assessment of Ni–B and Ni–B–C Systems (2022) [crossref_reference_list]
• Coupled pair potential, thermochemical and phase diagram data for transition metal binary systems-VII (1984) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• Thermodynamic evaluation of Cu– system based on newly determined Gibbs energy of formation of (2009) [crossref_reference_list]
• Experimental investigation and thermodynamic assessment of the Cu–Sn–Ti ternary system (2011) [crossref_reference_list]
• The Cu–Sn phase diagram part II: New thermodynamic assessment (2013) [crossref_reference_list]
• Thermodynamic optimization of the Cu–Sn and Cu–Nb–Sn systems (2009) [crossref_reference_list]
• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag–Sn, Cu–Sn and Ni–Sn intermetallic compounds (2007) [crossref_reference_list]
• Thermodynamic description of CuSnP system in the copper-rich corner (2001) [crossref_reference_list]
• A Calorimetric Investigation of Some Binary and Ternary Liquid Alloys Rich in Tin (1956) [crossref_reference_list]
• Heat of Formation of Solid and Liquid Binary Alloys of Copper with Cadmium, Indium, Tin and Antimony at 450° (1956) [crossref_reference_list]
• Thermodynamic Analysis of the Cu-Sn-P Ternary System (2011) [crossref_reference_list]
• Thermodynamic Assessment of the Cu-Sn System (1996) [crossref_reference_list]
• Cu₄SnP₁₀, a compound with decaphospha-adamantane anions P^6- ₁₀ and four-center [SnCu₃] clusters (1980) [crossref_reference_list]
• On the Equilibrium Diagram of Cu-Sn System (1938) [crossref_reference_list]
• Effects of Ca Addition on Solidification Structure of Cu-Sn-Zn Bronze Castings (2007) [crossref_reference_list]
• Measurement of Vapor Pressure of Phosphorus over Sn–P Alloys by Dew Point Method (1985) [crossref_reference_list]
• Thermodynamic description of the system Cu–Sn–P experimental and numerical investigation (2012) [crossref_reference_list]

Cites (values carry this citation) (9)

• Über das Zustandsschaubild der CuSnP‐Legierungen (1933) — 9 values [orchid_extraction]
• Thermodynamic description of CuSnP system in the copper-rich corner (2001) — 8 values [orchid_extraction]
• Thermodynamic Analysis of the Cu-Sn-P Ternary System (2011) — 8 values [orchid_extraction]
• Cu₄SnP₁₀, a compound with decaphospha-adamantane anions P^6- ₁₀ and four-center [SnCu₃] clusters (1980) — 8 values [orchid_extraction]
• Effects of Ca Addition on Solidification Structure of Cu-Sn-Zn Bronze Castings (2007) — 8 values [orchid_extraction]
• Thermodynamic description of the system Cu–Sn–P experimental and numerical investigation (2012) — 8 values [orchid_extraction]
• On the Equilibrium Diagram of Cu-Sn System (1938) — 4 values [orchid_extraction]
• Phase diagram of the Sn–P system (2018) — 2 values [orchid_extraction]
• Measurement of Vapor Pressure of Phosphorus over Sn–P Alloys by Dew Point Method (1985) — 1 values [orchid_extraction]

TDB files modelling its system (3)

• tdb:CuP-24Oik.tdb [sgte_tdb_header]
• tdb:CuSn-24Oik.tdb [sgte_tdb_header]
• tdb:SnP-24Oik.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (7)

• Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems (2004) [citation+same-system]
• Thermodynamic evaluation of Cu– system based on newly determined Gibbs energy of formation of (2009) [citation+same-system]
• Experimental investigation and thermodynamic assessment of the Cu–Sn–Ti ternary system (2011) [citation+same-system]
• The Cu–Sn phase diagram part II: New thermodynamic assessment (2013) [citation+same-system]
• Thermodynamic description of CuSnP system in the copper-rich corner (2001) [citation+same-system]
• Thermodynamic Analysis of the Cu-Sn-P Ternary System (2011) [citation+same-system]
• Thermodynamic Assessment of the Cu-Sn System (1996) [citation+same-system]

Data papers used (9)

• Über das Zustandsschaubild der CuSnP‐Legierungen (1933) — 9 values [orchid_extraction]
• Thermodynamic description of CuSnP system in the copper-rich corner (2001) — 8 values [orchid_extraction]
• Thermodynamic Analysis of the Cu-Sn-P Ternary System (2011) — 8 values [orchid_extraction]
• Cu₄SnP₁₀, a compound with decaphospha-adamantane anions P^6- ₁₀ and four-center [SnCu₃] clusters (1980) — 8 values [orchid_extraction]
• Effects of Ca Addition on Solidification Structure of Cu-Sn-Zn Bronze Castings (2007) — 8 values [orchid_extraction]
• Thermodynamic description of the system Cu–Sn–P experimental and numerical investigation (2012) — 8 values [orchid_extraction]
• On the Equilibrium Diagram of Cu-Sn System (1938) — 4 values [orchid_extraction]
• Phase diagram of the Sn–P system (2018) — 2 values [orchid_extraction]
• Measurement of Vapor Pressure of Phosphorus over Sn–P Alloys by Dew Point Method (1985) — 1 values [orchid_extraction]