The Cu–Sn phase diagram part II: New thermodynamic assessment

D. Li, P. Franke, S. Fürtauer, D. Cupid, H. Flandorfer

Intermetallics 34 148-158 (2013) · Elsevier BV

DOI: 10.1016/j.intermet.2012.10.010

Data: JSON record · id doi:10.1016/j.intermet.2012.10.010 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 53 released values
• cited as the original source of values
• assessment behind a TDB file: CuSn-13Li.tdb (Cu–Sn)
• discovery lead (found by Crossref assessment discovery, not read): rank 1063, score 93; systems named in title: none

Systems

Cu–Sn

Evidence in ORCHID

53 values read from this paper (51 accepted), from 2 tables and 2 text passages.

1 values in 1 other papers cite this work as their source.

ESPEI datasets derived: 2 (derived/invariant-brackets/CU-SN/CuSn-13Li.zpf-00.json …).

Phase-registry phases citing it: phase:cu-sn:a4-diamond, phase:cu-sn:a5-bct, phase:cu-sn:bcc-4sl, phase:cu-sn:bcc-a2, phase:cu-sn:cu10sn3, phase:cu-sn:cu3sn-l, phase:cu-sn:cu41sn11, phase:cu-sn:cu6sn5-b81, phase:cu-sn:cu6sn5-l, phase:cu-sn:fcc-a1, phase:cu-sn:hcp-a3, phase:cu-sn:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 144 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (23)

• Nucleation and Growth of Cu-Al Intermetallics in Al-Modified Sn-Cu and Sn-Ag-Cu Lead-Free Solder Alloys (2015) [crossref_reference_list]
• Phase Equilibria of the Cu-Si-Sn System at 700 and 500 °C (2015) [crossref_reference_list]
• Phase Equilibria of the Cu-Sn-Bi Ternary System (2016) [crossref_reference_list]
• The Isothermal Section of the Zr-Sn-Cu Ternary System at 700 °C (2018) [crossref_reference_list]
• Phase Equilibria in the Cu-Sn-Sb Ternary System (2018) [crossref_reference_list]
• Thermodynamic Modeling of the Co-Cu-Sn Ternary System (2022) [crossref_reference_list]
• Thermodynamic Reassessment of the Binary Cu-Sn, Cu-P, and Sn-P and Ternary Cu-Sn-P Systems (2024) [crossref_reference_list]
• Thermodynamic assessment of the Cu–Li system and prediction of enthalpy of mixing of Cu–Li–Sn liquid alloys (2016) [crossref_reference_list]
• Experimental study and thermodynamic modeling of the Cu–Sn–Si–O system and sub-systems (2021) [crossref_reference_list]
• Thermodynamic descriptions of the binary Ni–Sn and ternary Cu–Ni–Sn systems over entire composition range: A revisit (2021) [crossref_reference_list]
• The SGTE collection of binary datasets (2025) [crossref_reference_list]
• Thermodynamic reassessment of Au–Cu–Sn ternary system (2014) [crossref_reference_list]
• The Cu-Li-Sn phase diagram: Isothermal sections (2016) [crossref_reference_list]
• Experimental thermodynamic study of the Cu-Li-Sn system by Knudsen Effusion Mass Spectrometry (2016) [crossref_reference_list]
• Effects of Sb addition on the properties of Sn-Ag-Cu/(Cu, Ni) solder systems (2016) [crossref_reference_list]
• Formation enthalpies of various ternary intermetallic compounds in the Cu-Li-Sn system (2019) [crossref_reference_list]
• Experimental investigation and thermodynamic description of the Cu-Sn-Zr ternary system (2025) [crossref_reference_list]
• The experimental phase equilibria studies of the Cu-Sn-S system (2026) [crossref_reference_list]
• Calorimetric studies of Cu–Li, Li–Sn, and Cu–Li–Sn (2013) [crossref_reference_list]
• Sn-Bi-Cu phase equilibria and directionally solidified alloys (2027) [crossref_reference_list]
• The Cu-Li-Sn Phase Diagram: Isopleths, Liquidus Projection and Reaction Scheme (2016) [crossref_reference_list]
• Phase diagram, thermodynamic investigations, and modelling of systems relevant to lithium-ion batteries (2017) [crossref_reference_list]
• Thermodynamic Modeling of the Ag-Cu-Sn Ternary System (2022) [crossref_reference_list]

References (Crossref, publisher-deposited) (14)

• Beiträge zur systematischen Verwandtschaftslehre XXVIII. Über die Bildungswärmen intermetallischer verbindungen V. Kobalt‐ Aluminiumlegierunge n; Kupferlegierungen (1924) [crossref_reference_list]
• An x-ray diffraction and calorimetric investigation of the compound Cu6Sn5 (1973) [crossref_reference_list]
• Thermodynamic description of the Cu-Al-Sn system in the copper-rich corner (2002) [crossref_reference_list]
• Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems (2004) [crossref_reference_list]
• Experimental and thermodynamic assessment of Sn-Ag-Cu solder alloys (2000) [crossref_reference_list]
• Experimental determination and thermodynamic calculation of the phase equilibria in the Cu-In-Sn system (2001) [crossref_reference_list]
• The Thermo-Calc databank system (1985) [crossref_reference_list]
• Experimental investigation and thermodynamic assessment of the Cu–Sn–Ti ternary system (2011) [crossref_reference_list]
• Thermodynamic optimization of the Cu–Sn and Cu–Nb–Sn systems (2009) [crossref_reference_list]
• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag–Sn, Cu–Sn and Ni–Sn intermetallic compounds (2007) [crossref_reference_list]
• Algebraic Representation of Thermodynamic Properties and the Classification of Solutions (1948) [crossref_reference_list]
• A Calorimetric Investigation of Some Binary and Ternary Liquid Alloys Rich in Tin (1956) [crossref_reference_list]
• Heat of Formation of Some Solid and Liquid Binary Alloys of Gold with Cadmium, Indium, Tin and Antimony (1956) [crossref_reference_list]
• Thermodynamic assessment of the Al–Li system (2007) [crossref_reference_list]

Cited for values by (1)

• Thermodynamic reassessment of Au–Cu–Sn ternary system (2014) — 1 values [orchid_extraction]

Cites (values carry this citation) (4)

• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag–Sn, Cu–Sn and Ni–Sn intermetallic compounds (2007) — 3 values [orchid_extraction]
• A Calorimetric Investigation of Some Binary and Ternary Liquid Alloys Rich in Tin (1956) — 2 values [orchid_extraction]
• Beiträge zur systematischen Verwandtschaftslehre XXVIII. Über die Bildungswärmen intermetallischer verbindungen V. Kobalt‐ Aluminiumlegierunge n; Kupferlegierungen (1924) — 1 values [orchid_extraction]
• An x-ray diffraction and calorimetric investigation of the compound Cu6Sn5 (1973) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:CuSn-13Li.tdb [orchid_literature_model_link]
• tdb:CuSn-13Li.tdb [sgte_tdb_header]

Reassessed by (2)

• Thermodynamic Reassessment of the Binary Cu-Sn, Cu-P, and Sn-P and Ternary Cu-Sn-P Systems (2024) [citation+same-system]
• Thermodynamic reassessment of Au–Cu–Sn ternary system (2014) [citation+same-system]

Reassesses (cites an earlier assessment of the same system) (3)

• Thermodynamic description of the Cu-Al-Sn system in the copper-rich corner (2002) [citation+same-system]
• Experimental investigation and thermodynamic calculation of the phase equilibria in the Cu-Sn and Cu-Sn-Mn systems (2004) [citation+same-system]
• Experimental investigation and thermodynamic assessment of the Cu–Sn–Ti ternary system (2011) [citation+same-system]

Data papers used (4)

• Interfaces in lead-free solder alloys: Enthalpy of formation of binary Ag–Sn, Cu–Sn and Ni–Sn intermetallic compounds (2007) — 3 values [orchid_extraction]
• A Calorimetric Investigation of Some Binary and Ternary Liquid Alloys Rich in Tin (1956) — 2 values [orchid_extraction]
• Beiträge zur systematischen Verwandtschaftslehre XXVIII. Über die Bildungswärmen intermetallischer verbindungen V. Kobalt‐ Aluminiumlegierunge n; Kupferlegierungen (1924) — 1 values [orchid_extraction]
• An x-ray diffraction and calorimetric investigation of the compound Cu6Sn5 (1973) — 1 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• Thermodynamic reassessment of Au–Cu–Sn ternary system (2014) — 1 values [orchid_extraction]